Title: Multivariate optimization approach applied to natural polymers from Ceratonia siliqua L. and Moringa oleifera Lam as coagulating/flocculating agents

Abstract

In this study, a multivariate 23 experimental design was applied to optimize the operational conditions (seed mass, salt concentration and pH) to employ Ceratonia siliqua L. (carob) and Moringa oleifera Lam (moringa) as coagulating/flocculating agents for water treatment. Currently, the coagulation stage in water treatment uses aluminium compounds, due to the characteristic reaction to natural alkalinity in raw water and for its low market value. Considering that aluminium effects on human health are not sufficiently studied to acknowledge its toxicity, and its significant environmental impacts, it is suitable for the studies to search for alternatives to be employed in the water treatment that will be distributed to human consumption. This study was carried out with raw water of high turbidity level, 83.7 NTU. The raw water collected was also characterized according to pH, colour, Total Organic Carbon (TOC), Dissolved Organic Carbon (DOC), and Dissolved Organic Matter (DOM), with values of 6.7, 178 NTU, 6.80, 2.45 and 138.58 mg/L respectively. The optimized results showed that with 2 g of seed, 0.5 mol L−1 of NaCl and pH 11.0 In these conditions, moringa coagulant reached 90%, 86%, 6%, 67%, and 81% for turbidity, colour, DOC, TOC, and DOM removal respectively, whereas the carob coagulant achieved 85%, 76%, 5%, 55.6%, 66.7% respectively for the same parameters’ removal. Both coagulants presented lower sludge formation, 1.1 mL L−1 for moringa coagulant, and 1.1 mL L−1 for carob coagulant. The results could be considered promises and natural polymers carob and moringa can be suggested as alternatives agents in coagulation/flocculation stages for water treatment.

Biography

Flavia Vieira da Silva-Medeiros graduated, masters and doctorate in Chemical Engineering from the State University of Maringá (Brazil), the latter with an internship period at the University of Minho (Portugal). She is currently an associate professor at the Federal University of Technology - Campo Mourão Campus. She is also a dual-degree advisor at the Polytechnic Institute of Bragança and permanent professor at the Postgraduate Program in Technological Innovations and at the Professional Master in National Network in Management and Regulation of Water Resources. She has experience in Chemical Engineering and Sanitary Engineering, acting on the following topics: production of drinking water, water resources and environmental sanitation.